Date of
Consecration | Bishop Ordinaries of Venezuela (68) |
| 1983.09.17 (2016.11.19) |  Cardinal Baltazar Enrique Porras Cardozo (81), Cardinal-Priest of Ss. Giovanni Evangelista e Petronio and Metropolitan Archbishop emeritus of Caracas (Venezuela) |
| 1990.05.27 (2023.09.30) | Cardinal Diego Rafael Padrón Sánchez (86), Cardinal-Priest of S. Gaetano and Metropolitan Archbishop emeritus of Cumaná (Venezuela) |
| 1971.03.19 (1992.12.23) |  Archbishop Ramón Ovidio Pérez Morales (93), Archbishop-Bishop emeritus of Los Teques (Venezuela) |
| 1990.05.27 (2000.11.11) | Archbishop Ubaldo Ramón Santana Sequera, F.M.I. (84), Metropolitan Archbishop emeritus of Maracaibo (Venezuela) |
| 1997.05.24 (2008.12.10) |  Archbishop Manuel Felipe Díaz Sánchez (70), Metropolitan Archbishop of Calabozo (Venezuela) |
| 2011.02.05 (2011.01.08) | Archbishop Edgar Peña Parra (66), Titular Archbishop of Thelepte, Apostolic Nuncio to San Marino and Apostolic Nuncio to Italy |
| 2004.02.27 (2011.08.27) | Archbishop Ulises Antonio Gutiérrez Reyes, O. de M. (74), Metropolitan Archbishop of Ciudad Bolívar (Venezuela) |
| 2016.05.28 (2016.03.19) | Archbishop Francisco Escalante Molina (61), Titular Archbishop of Gratiana and Apostolic Nuncio to Japan |
| 1994.10.28 (2016.10.25) | Archbishop Mariano José Parra Sandoval (78), Metropolitan Archbishop emeritus of Coro (Venezuela) |
| 1999.05.29 (2018.05.24) | Archbishop José Luis Azuaje Ayala (68), Metropolitan Archbishop of Maracaibo (Venezuela), Vice-President of Episcopal Conference of Venezuela and First Vice-President of Latin American Episcopal Council |
| 2008.01.12 (2018.05.24) | Archbishop Jesús Andoni González de Zárate Salas (65), Metropolitan Archbishop of Valencia (Venezuela) and President of Episcopal Conference of Venezuela |
| 2017.09.23 (2022.03.19) | Archbishop Helizandro Emiro Terán Bermúdez, O.S.A. (60), Metropolitan Archbishop of Mérida (Venezuela) |
| 2016.05.21 (2023.10.31) | Archbishop Víctor Hugo Basabe (64), Metropolitan Archbishop of Coro (Venezuela) |
| 2014.02.08 (2024.06.28) | Archbishop Raúl Biord Castillo, S.D.B. (63), Metropolitan Archbishop of Caracas (Venezuela) |
| 2016.06.18 (2024.06.28) | Archbishop Polito Rodríguez Méndez (58), Metropolitan Archbishop of Barquisimeto (Venezuela) |
| 2013.02.16 (2025.03.06) | Archbishop Ángel Francisco Caraballo Fermín (60), Metropolitan Archbishop of Cumaná (Venezuela) |
| 1982.03.25 |  Bishop Nelson Antonio Martínez Rust (81), Bishop emeritus of San Felipe (Venezuela) |
| 1986.01.06 | Bishop Felipe González González, O.F.M. Cap. (81), Titular Bishop of Sinnuara and Vicar Apostolic emeritus of Caroní (Venezuela) |
| 1994.04.23 | Bishop Freddy Jesús Fuenmayor Suárez (76), Bishop emeritus of Los Teques (Venezuela) |
| 1994.10.15 | Bishop Ramón Antonio Linares Sandoval (89), Bishop emeritus of Barinas (Venezuela) |
| 1995.12.16 | Bishop William Enrique Delgado Silva (75), Bishop emeritus of Cabimas (Venezuela) |
| 1995.12.21 | Bishop Georges Kahhalé Zouhaïraty, B.A. (87), Titular Bishop of Abila Lysaniæ and Apostolic Exarch emeritus of Venezuela of the Greek-Melkites (Venezuela) |
| 1996.01.20 |  Bishop Jesús Alfonso Guerrero Contreras, O.F.M. Cap. (75), Bishop of Barinas (Venezuela) |
| 1996.05.04 | Bishop José Angel Divassón Cilveti, S.D.B. (86), Titular Bishop of Bamaccora and Vicar Apostolic emeritus of Puerto Ayacucho (Venezuela) |
| 1997.01.11 | Bishop Gustavo García Naranjo (81), Bishop emeritus of Guarenas (Venezuela) |
| 1997.04.19 | Bishop José de la Trinidad Valera Angulo (78), Bishop emeritus of Guanare (Venezuela) |
| 1997.04.26 | Bishop Ramiro Díaz Sánchez, O.M.I. (91), Titular Bishop of Lari Castellum and Vicar Apostolic emeritus of Machiques (Venezuela) |
| 1998.01.10 | Bishop Saúl Figueroa Albornoz (78), Bishop emeritus of Puerto Cabello (Venezuela) |
| 2002.01.12 |  Bishop Luis Alfonso Márquez Molina, C.I.M. (89), Titular Bishop of Turris rotunda and Auxiliary Bishop emeritus of Mérida (Venezuela) |
| 2003.03.15 | Bishop Jesús Tomás Zárraga Colmenares (68), Bishop emeritus of San Carlos de Venezuela (Venezuela) |
| 2003.10.31 | Bishop Enrique Pérez Lavado (74), Bishop of Maturín (Venezuela) |
| 2004.05.22 | Bishop Ramón José Aponte Fernández (77), Bishop emeritus of Valle de la Pascua (Venezuela) |
| 2007.04.28 | Bishop Luis Armando Tineo Rivera (77), Bishop emeritus of Carora (Venezuela) |
| 2007.09.16 | Bishop Daniel Kozlinski Netto (74), Bishop of Santa María del Patrocinio en Buenos Aires of the Ukrainians (Argentina) and Apostolic Visitator in Uruguay, Paraguay, Chile and Venezuela of the Ukrainians |
| 2009.03.07 | Bishop Jorge Anibal Quintero Chacón (69), Bishop of Barcelona (Venezuela) |
| 2009.09.26 | Bishop Fernando José Castro Aguayo, Opus Dei (74), Bishop of Margarita (Venezuela) |
| 2010.06.26 | Bishop Jaime José Villarroel Rodríguez (63), Bishop of Carúpano (Venezuela) |
| 2011.05.22 | Bishop Timoteo Hikmat Beylouni (80), Apostolic Exarch of Venezuela of the Syriacs (Venezuela) and Titular Bishop of Sabrata |
| 2012.04.14 | Bishop José Manuel Romero Barrios (71), Bishop of El Tigre (Venezuela) |
| 2012.07.08 | Bishop Tulio Luis Ramírez Padilla (66), Bishop of Guarenas (Venezuela) |
| 2013.09.13 | Bishop Alfredo Enrique Torres Rondón (76), Bishop emeritus of San Fernando de Apure (Venezuela) |
| 2014.07.06 | Bishop José Trinidad Fernández Angulo (61), Bishop of Trujillo (Venezuela) |
| 2015.07.04 | Bishop Juan de Dios Peña Rojas (58), Bishop of El Vigía–San Carlos del Zulia (Venezuela) |
| 2015.07.10 | Bishop Benito Adán Méndez Bracamonte (63), Military Ordinary of Venezuela (Venezuela) |
| 2015.07.12 | Bishop Ernesto José Romero Rivas, O.F.M. Cap. (65), Vicar Apostolic of Tucupita (Venezuela) and Titular Bishop of Nova Sparsa |
| 2015.10.24 | Bishop Juan Carlos Bravo Salazar (58), Bishop of Petare (Venezuela) |
| 2016.01.10 | Bishop Jonny Eduardo Reyes Sequera, S.D.B. (73), Vicar Apostolic of Puerto Ayacucho (Venezuela) and Titular Bishop of Canapium |
| 2016.02.06 | Bishop Pablo Modesto González Pérez, S.D.B. (66), Bishop of La Guaira (Venezuela) |
| 2016.07.09 | Bishop Enrique José Parravano Marino, S.D.B. (70), Bishop of Maracay (Venezuela) |
| 2016.08.06 | Bishop Carlos Alfredo Cabezas Mendoza (60), Bishop of Ciudad Guayana (Venezuela) |
| 2017.09.29 | Bishop Luis Enrique Rojas Ruiz (57), Bishop of Punto Fijo (Venezuela) |
| 2019.03.19 | Bishop Carlos Enrique Curiel Herrera, Sch. P. (65), Bishop of Carora (Venezuela) and Second Vice-President of Episcopal Conference of Venezuela |
| 2019.11.23 | Bishop Ricardo Aldo Barreto Cairo (57), Bishop of Valle de la Pascua (Venezuela) |
| 2019.12.14 | Bishop Nicolás Gregorio Nava Rojas (62), Bishop of Machiques (Venezuela) |
| 2020.03.07 | Bishop Joseph Antoine Khawam, B.A. (57), Apostolic Exarch of Venezuela of the Greek-Melkites (Venezuela), Titular Bishop of Apamea in Syria of the Greek-Melkites and Apostolic Administrator of Nuestra Señora del Paraíso en México of the Greek-Melkites (Mexico) |
| 2020.12.12 |  Bishop Juan Alberto Ayala Ramírez (52), Titular Bishop of Rusibisir and Auxiliary Bishop of San Cristóbal de Venezuela (Venezuela) |
| 2021.06.26 | Bishop Gonzalo Alfredo Ontiveros Vivas (57), Vicar Apostolic of Caroní (Venezuela) |
| 2022.03.12 | Bishop Carlos Eduardo Márquez Delima (64), Titular Bishop of Cefala and Auxiliary Bishop of Caracas (Venezuela) |
| 2022.03.12 | Bishop Lisandro Alirio Rivas Durán, I.M.C. (56), Bishop of San Cristóbal de Venezuela (Venezuela) |
| 2022.11.05 | Bishop Gerardo Ernesto Salas Arjona (59), Bishop of Acarigua–Araure (Venezuela) |
| 2023.07.01 | Bishop Oswaldo Enrique Araque Valero (61), Bishop of Guanare (Venezuela) |
| 2024.07.06 | Bishop José Antonio Da Conceição Ferreira (55), Bishop of Puerto Cabello (Venezuela) and General Secretary of Episcopal Conference of Venezuela |
| 2025.02.08 | Bishop Rubén Gregorio Delgado Carmona (62), Bishop of San Felipe (Venezuela) |
| 2025.08.23 | Bishop Alexander Rivera Vielma (52), Bishop of San Carlos de Venezuela (Venezuela) |
| 2026.02.21 | Bishop Elieser Antonio Rivero Barrios (50), Bishop of San Fernando de Apure (Venezuela) |
| 2026.04.25 | Bishop-elect Alberto Valentín Castillo García (56), Bishop of Los Teques (Venezuela) |
| 2026.07.11 | Bishop-elect José Manuel León, C.P. (59), Titular Bishop of Gigthi and Auxiliary Bishop of Caracas (Venezuela) |
| 2026.07.11 | Bishop-elect José Dionisio Gómez Gouveia (59), Titular Bishop of Fuerteventura and Auxiliary Bishop of Caracas (Venezuela) |
