Date | Protonotaries Apostolic Supernumerary (1) |
| 2001.07.09 | Msgr. Luis Eugenio Silva Cuevas |
| Date | Prelates of Honour (1) |
| 2009.06.19 | Msgr. Mario Fernando Retamal Fuentes |
| Date | Chaplains of His Holiness (28) |
| 2010.03.18 | Msgr. Alonso Rodrigo Bilbao Zepeda |
| 2009.05.20 | Msgr. Sidney Fones Infante |
| 2005.12.05 | Msgr. Damián Acuña Jarpa |
| 2005.12.05 | Msgr. Héctor Gallardo Villalobos |
| 2003.12.10 | Msgr. Fernando Ramos Pérez |
| 2003.06.30 | Msgr. Ignacio Muñoz Muñoz |
| 2003.06.30 | Msgr. Juan de la Cruz Suárez Campos |
| 2003.06.30 | Msgr. Pedro Narbona Bugueño |
| 1998.06.24 | Msgr. Ignácio Ducasse Medina |
| 1996.11.18 |  Msgr. Cristián Contreras Villarroel (now Bishop) |
| 1988.05.11 | Msgr. Felipe Bacarreza Rodríguez |
| 1982.01.09 | Msgr. Alfonso Puelma Claro |
| 1982.01.09 | Msgr. Bernardo Herrera Salas |
| 1982.01.09 | Msgr. Daniel Iglesias Beaumont |
| 1982.01.09 | Msgr. Eduardo Canessa Ibarra |
| 1982.01.09 | Msgr. Fernando Alliendo Donoso |
| 1982.01.09 | Msgr. Fidel Araneda Bravo |
| 1982.01.09 | Msgr. Iván Larraín Eyzaguirre |
| 1982.01.09 | Msgr. Joaquín Aguiar González |
| 1982.01.09 | Msgr. Joaquín José Matte Varas |
| 1982.01.09 | Msgr. Jorge Arturo Augusto Medina Estévez |
| 1982.01.09 | Msgr. Jorge Arturo Medina Estévez (later Cardinal) |
| 1982.01.09 | Msgr. José Hermogenes De La Cerda Plaza |
| 1982.01.09 | Msgr. Luis Ernesto Dalbadie Valdés |
| 1982.01.09 | Msgr. Pedro Muñoz Valderrama |
| 1982.01.09 | Msgr. Romelio Carreño Atenas |
| 1982.01.09 | Msgr. Santiago Tapia Carvajal |
| 1982.01.09 | Msgr. Vicente Ahumada Prieto |
